Product Details
Overview of Pyrolytic Boron Nitride (PBN) Ceramic Tubes
1.1 General introduction
Pyrolytic Boron Nitride (PBN) ceramic tube is a high-performance hollow cylindrical ceramic with prominent anisotropic properties, ultra-high vacuum tightness, outstanding high-voltage insulation and directional thermal conductivity. It delivers precise directional heat control, radiation resistance and low gas release, widely adopted in ultra-high vacuum, semiconductor and high-temperature precision testing equipment, as an irreplaceable advanced ceramic different from alumina, AlN and hot-pressed boron nitride.
1.2 Chemical Composition & Microstructure
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Single-phase pure boron nitride ceramic, ultra-high purity crystal structure formed by vapor deposition, minimal impurity elements.
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Distinct layered hexagonal crystal lattice, showing obvious anisotropy on thermal and mechanical performance between a-axis and c-axis directions.
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Apparent density: 2.10–2.15 g/cm³ for plate blanks, 2.15–2.19 g/cm³ for crucible tubes; dense pore-free structure with extremely low helium transmittance.
2. Manufacturing Process
2.1 Vapor Deposition Raw Material Preparation
High-purity boron source and nitrogen carrier gas are precisely proportioned, purified to eliminate particle impurities, strictly controlled gas flow to guarantee uniform crystal deposition and stable layered lattice growth.
Step A: High-temperature vapor reaction under sealed furnace at controlled thermal gradient.
Step B: Slow layered crystal deposition to form complete uniform hexagonal BN layers.
Step C: Form integrated compact PBN tube blank without internal pores or microcracks.
Step D: Strictly constant temperature curve to avoid deformation and internal stress during deposition.
2.2 Precision Cutting & Controllable Machining
Step A: Mould forming of hollow tubular blanks via self-designed fixture after deposition.
Step B: Slow programmed cutting to eliminate uneven internal stress inside tube bodies.
Step C: Cooled tube blanks maintain complete round shape without deformation before post-processing.
Secondary annealing treatment to release residual forming stress, improve tube body toughness and avoid cracking during precision machining.
2.3 Blank Cutting & Stock Shaping
Saw large sintered PBN blank into standard semi-finished tubular stock; grind inner & outer tube surfaces to uniform dimensional standards for commercial inspection tubes for internal defect detection, annealing treatment eliminates surface residual stress, visual rejecting defective blanks. These semi-finished tubular stock is raw material supply to component manufacturers.
3. Core Performance Profile (Defining Feature)
3.1 Distinct Anisotropic Thermal Performance
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Directional thermal conductivity: 60 W/m·k along a-axis & only 2.60 W/m·k along c-axis at 200℃, realizing one-way heat conduction & vertical heat insulation for precision temperature control scenarios.
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Stable long-term service under alternating hot & cold cycles, excellent thermal shock resistance without cracking or deformation.
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Ultra-low helium transmittance at 1×10⁻¹⁰ cm³/s, perfect compatibility with ultra-high vacuum (UHV) chambers.
3.2 Excellent Electrical Insulation
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Volume resistivity reaches 3.11×10¹¹ Ω·cm, maintains stable insulation across wide temperature & frequency ranges.
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Extra-high dielectric strength up to 56 KV/mm at room temperature, reliable isolation under ultra-high voltage working conditions.
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Stable insulation property under continuous high-frequency radiation, far superior to polymer plastics which degrade rapidly under high temperature & radiation.
3.3 Chemical & Vacuum Compatibility
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Inert to most acids, alkalis, organic solvents and oils; only slightly corroded by hydrofluoric acid and strong molten alkali metals.
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Zero gas release under ultra-high vacuum, non-polluting to semiconductor wafer and optical component processing environments.
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Outstanding radiation stability against X-ray, gamma and particle irradiation, suitable for nuclear energy and aerospace precision fixtures.
3.4 Mechanical & Safety Performance
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Anisotropic mechanical strength: bending strength 243.63 N/mm² (force parallel to c-axis), 197.76 N/mm² (force perpendicular to c-axis), flexible machinability for complex tube profiles.
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Knoop microhardness 691.88 N/mm², moderate hardness allowing easy cutting, drilling and turning without severe tool abrasion.
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Non-toxic inorganic material without volatile organics, safe for electronic, medical and nuclear industry equipment.
- Dense seamless tube wall structure, long service life under continuous fluid or gas flushing in vacuum furnaces.



4. Key Limitations
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Not suitable for long-term working under molten strong alkali metal environment, slight surface corrosion will occur.
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Thermal conductivity differs sharply between two crystal directions, directional layout design must be reserved in fixture drawing.
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Higher material cost than hot-pressed boron nitride, not the first choice for low-cost ordinary high-temperature insulation parts.
5. Main Industrial Applications
5.1 Vacuum & Semiconductor
UHV chamber isolation sleeves, wafer heating directional thermal barriers, electron beam equipment insulation tubes, semiconductor film deposition crucible liners.
5.2 Aerospace & Radiation Testing
Satellite precision thermal isolation sleeves, space radiation shielding structural brackets, particle accelerator high-voltage insulation tubes.
5.3 High-Voltage Precision Electronics
Radio frequency coil isolation sleeves, high-frequency power supply insulation liners, laser resonant cavity temperature control tubes.
5.4 Optics & Precision Instruments
Optical base heating sleeves, electron microscope internal isolation fittings, precision metrology equipment temperature-controlled fixture tubes.
5.5 Medical & Nuclear Industry
Radiation shielding test jigs, non-contaminating laboratory positioning sleeves, nuclear reactor low-loss radiation protection insulation tubes.
6. Material Positioning
Pyrolytic Boron Nitride (PBN) ceramic tube fills the performance gap between ordinary hot-pressed BN and aluminum nitride ceramics. It provides ultra-high vacuum tightness, anisotropic thermal control and superior radiation resistance. Compared with hot pressed BN, PBN features zero air permeability and much higher dielectric strength; compared with AlN, PBN achieves one-way heat isolation while retaining full high-frequency insulation stability. It is the preferred high-performance hollow tube material for customized precision components working under ultra-high vacuum, strong radiation and precise temperature gradient environments.
Parameter
| Item |
Unit |
Index |
| Thermal Conductivity (RT) |
W/m·k |
45 - 50 |
| Thermal expansivity (25 - 700℃) |
10⁻⁶/℃ |
6.5 - 7.5 |
| Resistivity (RT) |
Ω·m |
>10¹² |
| Puncture voltage |
10⁶ kv/m |
2.5 - 4.0 |
| Mohs' hardness |
- |
2 |
| Dielectric constant (Σ) |
- |
3.8 - 4.3 |
| Bending strength (RT) |
mpa |
>35 |
| Compression strength (RT) |
mpa |
>200 |
| Density |
g/cm³ |
1.9 - 2.2 |
| Chemical Composition |
B + N |
% |
99.5 |
| Oxygen Content |
% |
<0.4 |
| Carbon Content |
% |
<0.02 |
| Working Environment Temperature |
Oxidizing Atmosphere |
℃ |
850 |
| Vacuum |
℃ |
1800 |
| Inertia |
℃ |
2300 |
Development History

Patents and certification
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FAQ
01
Question: Can you produce based on customers’ drawings or physical samples?
Answer: Absolutely yes. We accept technical drawings in all mainstream file formats as well as actual physical samples. Before formal production, our engineering team will provide a full professional DFM feasibility evaluation for your reference.
02
Question: How long is the production lead time for custom orders?
Answer: Sample lead time: 3–7 working days. Custom mold lead time: 5–10 working days (we will confirm the cycle separately with you for complex molds). Mass production lead time: 7–20 working days, depending on product structure complexity and order quantity.
03
Question: What’s your minimum order quantity for custom products?
Answer: We provide flexible MOQ solutions for all customized items. We will try our best to set a low minimum order volume to support your small-batch trial orders, meanwhile we can handle stable mass production to satisfy your long-term bulk demands.
04
Question: What customization services can you provide?
Answer: We support comprehensive one-stop customization, including product size, shape, appearance, precision tolerance, surface treatment, hole grooving, bending, cutting and adjustable high-temperature resistant parameters. Custom engraved LOGO and exclusive customized packaging are also available as extra personalized options upon request.
05
Question: Do you accept third-party inspection of finished products?
Answer: Yes, we fully cooperate with all mainstream authorized third-party testing institutions. Well-known organizations such as SGS, BV and other internationally recognized inspection bodies are all acceptable. We can supply complete official inspection reports and material certification documents as you require.
06
Question: Can you customize raw material options for products?
Answer: Sure. We can select and match appropriate raw materials according to your application scenarios, working conditions and performance requirements, including alumina, zirconia, quartz, silicone and other special engineering materials, and adjust related performance parameters to meet your usage standards.